http://www.sciencedirect.com/science/article/pii/S1674987114000917

Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.     

http://www.sciencedirect.com/science/article/pii/S167498711300162X

Seismic observations have shown structural variation near the base of the mantle transition zone(MTZ)where subducted cold slabs,as visualized with high seismic speed anomalies(HSSAs),flatten to form stagnant slabs or sink further into the lower mantle.The different slab behaviors were also accompanied by variation of the "660 km" discontinuity depths and low viscosity layers(LVLs) beneath the MTZ that are suggested by geoid inversion studies.We address that deep water transport by subducted slabs and dehydration from hydrous slabs could affect the physical properties of mantle minerals and govern slab dynamics.A systematic series of three-dimensional numerical simulation has been conducted to examine the effects of viscosity reduction or contrast between slab materials on slab behaviors near the base of the MTZ.We found that the viscosity reduction of subducted crustal material leads to a separation of crustal material from the slab main body and its transient stagnation in the MTZ.The once trapped crustal materials in the MTZ eventually sink into the lower mantle within 20-30 My from the start of the plate subduction.The results suggest crustal material recycle in the whole mantle that is consistent with evidence from mantle geochemistry as opposed to a two-layer mantle convection model.Because of the smaller capacity of water content in lower mantle minerals than in MTZ minerals,dehydration should occur at the phase transformation depth,~660 km.The variation of the discontinuity depths and highly localized low seismic speed anomaly(LSSA) zones observed from seismic P waveforms in a relatively high frequency band(~1 Hz) support the hypothesis of dehydration from hydrous slabs at the phase boundary.The LSSAs which correspond to dehydration induced fluids are likely to be very local,given very small hydrogen(H~+) diffusivity associated with subducted slabs.The image of such local LSSA zones embedded in HSSAs may not be necessarily captured in tomography studies.The high electrical conductivity in the MTZ beneath the northwestern Pacific subduction zone does not necessarily require a broad range of high water content homogeneously.     

http://www.sciencedirect.com/science/article/pii/S1674987114001108

<正>About three decades after the establishment of the plate tectonics theory in the late 1960s,Maruyama(1994)proposed the"plume tectonics"theory based on whole-mantle seismic tomography image(Fukao,1992;Fukao et al.,1994).According to this theory,the earth's interior is divided into three regimes:the earth's surface region governed by lateral motions of tectonic plates,the mantle governed by vertical motions of"superplumes"(i.e.,large-     

Pressure and temperature dependence of the viscosity of a NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript> melt

The viscosity of a silicate melt of composition NaAlSi₂O₆ was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi₂O₆ melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 10² and 3.7 ± 0.5 × 10² kJ/mol at 2.2 and 2.9 GPa, respectively.     

Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH4-CO2 fluxes

Methane and CO₂ emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (δ¹³C_CH4 from −32.9‰ to −36.2‰), likely associated with oil, and enrichments of ¹³C in CO₂ (δ¹³C_CO2 up to +28.3‰) and propane (δ¹³C_C3H8 up to −8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 10¹-10⁴ g m⁻² d⁻¹ in macro-seeps, and up to 446 g m⁻² d⁻¹ from diffuse seepage. Positive CH₄ fluxes from dry soil were widespread throughout the investigated areas. Total CH₄ emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton a⁻¹, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO₂ fluxes were directly proportional to CH₄ fluxes, and the volumetric ratios between CH₄ flux and CO₂ flux were similar to the compositional CH₄/CO₂ volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the “Bernard ratio” C₁/(C₂ + C₃)) is inversely proportional to gas migration fluxes. The CH₄ “emission factor” (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global “emission-factor” data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH₄ emission from mud volcanoes may be significantly underestimated.     

Diagnostic metrics for evaluation of annual and diurnal cycles

Two sets of diagnostic metrics are proposed for evaluation of global models?? simulation of annual and diurnal cycles of precipitation. The metrics for the annual variation include the annual mean, the solstice and equinoctial asymmetric modes of the annual cycle (AC), and the global monsoon precipitation domain and intensity. The metrics for the diurnal variation include the diurnal range, the land?Csea contrast and transition modes of the diurnal cycle (DC), and the diurnal peak propagation in coastal regions. The proposed modes for the AC and DC represent faithfully the first two leading empirical orthogonal functions and explain, respectively, 82% of the total annual variance and 87% of the total diurnal variance over the globe between 45°S and 45°N. The simulated AC and DC by the 20-km-mesh MRI/JMA atmospheric general circulation model (AGCM) are in a wide-ranging agreement with observations; the model considerably outperforms any individual AMIP II GCMs and has comparable performance to 12-AMIP II model ensemble simulation measured by Pearson??s pattern correlation coefficient. Comparison of four versions of the MRI/JMA AGCM with increasing resolution (180, 120, 60, and 20?km) reveals that the 20-km version reproduces the most realistic annual and diurnal cycles. However, the improved performance is not a linear function of the resolution. Marked improvement of the simulated DC (AC) occurs at the resolution of 60?km (20?km). The results suggest that better represented parameterizations that are adequately tuned to increased resolutions may improve models?? simulation on the forced responses. The common deficiency in representing the monsoon domains suggests the models having difficulty in replicating annual march of the Subtropical Highs that is largely driven by prominent east-west land?Cocean thermal contrast. Note that the 20-km model reproduces realistic diurnal cycle, but fails to capture realistic Madden-Julian Oscillation.     

Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.     

Detection of large color variation in the potentially hazardousasteroid （297274） 1996 SK

Low-inclination near-earth asteroid(NEA)(297274) 1996 SK,which is also classified as a potentially hazardous asteroid,has a highly eccentric orbit.It was studied by multi-wavelength photometry within the framework of an NEA color survey at Lulin Observatory.Here,we report the finding of large color variation across the surface of(297274) 1996 SK within one asteroidal rotation period of4.656 ± 0.122 hours and classify it as an S-type asteroid according to its average colors of B- V = 0.767 ± 0.033,V- R = 0.482 ± 0.021,V- I = 0.801 ± 0.025and the corresponding relative reflectance spectrum.These results might be indicative of differential space weathering or compositional inhomogeneity in the surface materials.     

The inner solar system cratering record and the evolution of impactor populations

We review previously published and newly obtained crater size-frequency distributions in the inner solar system. These data indicate that the Moon and the terrestrial planets have been bombarded by two populations of objects. Population 1,dominating at early times, had nearly the same size distribution as the present-day asteroid belt, and produced heavily cratered surfaces with a complex, multi-sloped crater size-frequency distribution. Population 2, dominating since about 3.8–3.7 Gyr,had the same size distribution as near-Earth objects(NEOs) and a much lower impact flux, and produced a crater size distribution characterized by a differential –3single-slope power law in the crater diameter range 0.02 km to 100 km. Taken together with the results from a large body of work on age-dating of lunar and meteorite samples and theoretical work in solar system dynamics, a plausible interpretation of these data is as follows. The NEO population is the source of Population 2 and it has been in near-steady state over the past ～ 3.7–3.8 Gyr; these objects are derived from the main asteroid belt by size-dependent non-gravitational effects that favor the ejection of smaller asteroids. However, Population 1 was composed of main belt asteroids ejected from their source region in a size-independent manner, possibly by means of gravitational resonance sweeping during orbit migration of giant planets;this caused the so-called Late Heavy Bombardment(LHB). The LHB began some time before ～3.9 Gyr, peaked and declined rapidly over the next ～ 100 to 300 Myr,and possibly more slowly from about 3.8–3.7 Gyr to ～2 Gyr. A third crater population(Population S) consisted of secondary impact craters that can dominate the cratering record at small diameters.